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1 article(s) from Dodero, Veronica I

Photocontrolled DNA minor groove interactions of imidazole/pyrrole polyamides

Sabrina Müller,
Jannik Paulus,
Jochen Mattay,
Heiko Ihmels,
Veronica I. Dodero and
Norbert Sewald

Beilstein J. Org. Chem. 2020, 16, 60–70, doi:10.3762/bjoc.16.8

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Scheme 1: Pyrrole–imidazole–azobenzene polyamides and the dsDNA target sequences employed in this study.

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Scheme 2: Building blocks required for the synthesis of the photoswitchable Im/Py polyamides. A) Fmoc–Azo–OH 1...

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Figure 1: Section of the ¹H NMR (600 MHz) spectrum of polyamide P1. A) Initial thermal equilibrium. B) After ...

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Figure 2: E/Z isomer ratio of the polyamides P1–P3. Values were obtained from the respective ¹H NMR experimen...

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Figure 3: Titration experiments of target DNA sequences with P1–P3 in the photostationary Z-state and the the...

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Figure 4: Titration of DNA containing single mutations (in bold) with P1–P3 in the photostationary Z-state an...

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Published 09 Jan 2020

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